Product ID:C&H 14EX SPRAY DETERGENT
MSDS Date:11/05/1999
FSC:6850
NIIN:01-464-9441
Status Code:A
MSDS Number: CKRYC

C & H CHEMICAL

222 STARKEY STREET
SAINT PAUL, MN 55107
US

Emergency Phone: 800-228-5635 EXT 005

Info Phone: 651-227-4343

Cage: TO922

C AND H ENTERPRISES INC

SAINT PAUL, MN 55107 US

Telephone: 651-227-2485

Cage: 0ZAU9

SODIUM METASILICATE

CAS: 6834-92-0

RTECS: VV9275000

DIETHYLENE GLYCOL BUTYL ETHER

CAS: 112-34-5

RTECS: KJ9100000

TRIETHANOLAMINE

CAS: 102-71-6

RTECS: KL9275000

ACGIH TLV: 5 MG/M3

LD50 LC50 Mixture:NONE PROVIDED BY MFR.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: SEVERE IRRITATION, OR BURNS
POSSIBLE. SKIN: IRRITATION, OR BURNS POSSIBLE WITH PROLONGED
CONTACT. INHALATION OF PRODUCT OR MIST OF SOLUTION: IRRITATION OF
RESPIRATORY TRACT. SWALLOWING: IRRITAT ION OR BURNS OF MOUTH,
THROAT & STOMACH. STOMACH UPSET. CHRONIC: NONE EXPECTED BEYOND
ACUTE EFFECTS. CONTAINS LESS THAN 5% AMINES. THERE COULD POSSIBLY
BE LIVER OR DIDNEY EFFECTS WITH EXTENSIVE OVER E XPOSURE, BASED ON
ANIMAL STUDIES OF AMINES. ADDITIONALLY, SOME PEOPLE DEVELOP SKIN
SENSITIZATION TO AMINES.
Explanation of Carcinogenicity:THIS PRODUCT OR ITS INGREDIENTS HAVE NOT
BEEN IDENTIFIED AS A CARCINOGEN OR PROBABLE CARCINOGEN BY NTP, IARC
MONOGRAPHS, OR OSHA.
Effects of Overexposure:NONE PROVIDED BY MFR.
Medical Cond Aggravated by Exposure:DERMATITIS & SIMILAR SKIN
DISORDERS.

First Aid:EYE-IMMEDIATELY FLUSH WITH RUNNING WATER HOLDING EYE LIDS
APART. REMOVE CONTACT LENSES IF PRESENT, & CONTINUE FLUSHING FOR 15
MINS. GET MEDICAL ASID. SKIN-IMMEDIATELY FLUSH WITH COOL RUNNING
WATER FOR 15 MINS. REMOVE CONTAMINATED CLOTHING &WASH BEFORE
REUSE. IF IRRITATION OR BURN DEVELOPS & PERSISTS, GET MEDICAL
ADVICE OR AID. INHALED-REMOVE TO FRESH AIR. IMMEDIATELY CALL FOR
MEDICAL ADVICE OR AID IF BREATHING DIFFICULTY OR IRRITATION IS
SEVERE OR CONTINUES. SWALLOWED-RINSE MOUTH WITH WATER. DRINK WATER,
MILK OR OTHER FLUIDS TO DILUTE. DO NOT INDUCE VOMITING UNLESS
DIRECTED BY MEDICAL PERSONNE L. CALL FOR MEDICAL AID.

Extinguishing Media:AS NEEDED FOR SURROUNDING FIRE.
Fire Fighting Procedures:FOR ANY CHEMICAL FIRE WEAR SELF CONTAINED
BREATHING APPARATUS, & PROTECTIVE CLOTHING TO PREVENT CONTACT.
Unusual Fire/Explosion Hazard:NONE

Spill Release Procedures:SMALL SPILL, LESS THAN 2 POUNDS: RECOVE AS
PRACTICAL. FLUSH SPILL AREA TO DRAIN WITH EXCESS WATER.

Handling and Storage Precautions:STORAGE: KEEP CONTAINERS TICHTLY
CLOSED. KEEP PRODUCT DRY TO PREVENT DAKING. HANDLING: AVOID
UNNECESSARY CONTACT WITH PRODUCT. AVOID BREATHING PRODUCT DUST, OR
MISTS OF SOLUTION OF PRODUCT.
Other Precautions:WASH IMMEDIATELY AFTER CONTACT. WASH AFTER USE. CLEAN
UP SPILLS PROMPTLY TO PREVENT ACCIDENTAL CONTACT. PREVENT CONTACT
WITH INCOMPATABLE MATERIALS.

Respiratory Protection:NONE NORMALLY REQUIRED. NIOSH/MSHA APPROVED
RESPIRATOR WHERE CONDITIONS MAY CAUSE EXPOSURE LIMITS TO BE
EXCEEDED FROM DUST OF PRODUCT OR MISTS OF SOLUTIONS.
Ventilation:GENERAL OR LOCAL TO AVOID EXPOSURE TO IRRITATING PRODUCT
DUST OR MISTS OF SOLUTIONS.
Protective Gloves:CHEMICAL RESISTANT, IMPERMEABLE GLOVES AS NEEDED TO
PREVENT EXCESSIVE CONTACT.
Eye Protection:GLASSES, GOGGLES OR FACE SHIELD.
Other Protective Equipment:FULL BODY COVERING COVERING & SHOES AS
NEEDED TO PREVENT EXCESSIVE CONTACT. EYE WASH STATIONS IN THE WORK
AREA.
Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING AND WASH BEFORE
RESUE.
Supplemental Safety and Health

HCC:B3
Volatile Org Content %:1
pH:12+/-.5(2% SOL)
Solubility in Water:COMPLETE
Appearance and Odor:FREE FLOWING WHITE POWDER.

STRONG OXIDIZING AGENTS, STRONG ACIDS.
Stability Condition to Avoid:CONTACT WITH INCOMPATABLE MATERIALS.
Hazardous Decomposition Products:OXIDES OF CARBON & NITROGEN.
Conditions to Avoid Polymerization:WILL NOT OCCUR

Waste Disposal Methods:PRODUCT & UN-NEUTRALIZED SOLUTIONS ARE ALKALINE.
NORMALLY SEWER DISPOSABLE IN DILUTE SOLUTIONS. CHECK WITH LOCAL
AUTHORITIES ABOUT ANY POSSIBLE RESTRICTIONS.

Toxicological Information:NO DATA.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO DATA.

Transport Information:DOT INFORMATION-49 CFR 172.101. DOT DESCRIPTION:
NON-REGULATED BY D.O.T. CONTAINER/MODE: (POWDER) DRUM.

SARA Title III Information:DIETHYLENE GLYCOL BUTYL ETHER-IDENTIFIES
CHEMICAL INGREDIENTS SUBJECT TO REPORTING REQUIREMENTS OF SECTION
313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF
1986. THIS INFORMATION SHOU LD BE INCLUDED IN ALL MSDS'S THAT ARE
COPIED AND DISTRIBUTED FOR THIS MATERIAL. SARA 302 COMPONENTS-40
CFR 355 APPENDIX A: NONE. SECTION 311/312 HAZARD CLASS - 40 CFR
370.2 SARA 313 COMPONENTS - 40 CF R 372.65: DIETHYLENE GLYCOL BUTYL
ETHER.
Federal Regulatory Information:TSCA (UNITED STATES) THE INTENTIONAL
INGREDIENTS OF THIS PRODUCT ARE LISTED. CERCLA RQ-40 CFR 302.4 (A):
NONE LISTED.
State Regulatory Information:CALIFORNIA PROPOSITION 65: NONE.